This work considers the development of a new magnesium-manganese oxide reactive material for thermochemical energy storage that displays exceptional reactive stability, has a high volumetric energy density greater than 1600 MJ m −3, and releases heat at temperatures greater than 1000 °C. 2. Theoretical considerations
Comparison of oxygen absorbed and released by magnesium-manganese oxides of particle sizes 125–180 μm cycled between 1000 °C and 1500 °C at P O 2 = 0.2 atm.. Results of the cycling tests described above show that magnesium-manganese oxides have a high degree of reactive stability under high-temperature cycling.
The analysis shown in Fig. 3 indicates that an energy density of more than 850 kJ kg −1 is easily achievable with magnesium-manganese oxides if reduction is carried out in air at 1500⁰C and oxidation is carried out at 1000⁰C. The maximum efficiency is above 84% for all three manganese-to-magnesium ratios.
Investigations on thermochemical energy storage based on technical grade manganese-iron oxide in a lab-scale packed bed reactor Critical evaluation and thermodynamic modeling of the Mg–Mn–O (MgO–MnO–MnO2) system J. Am. Ceram.
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